Tetrakis( N ‐ethyl‐9‐oxo‐4‐azonia‐5‐aza‐9 H ‐fluorene) tetra‐μ 3 ‐iodo‐hexa‐μ 2 ‐iodo‐dodecaiodohexabismuthate | Zendy

Tershansy Meredith A. | Zendy; Goforth Andrea M. | Zendy; Smith Mark D. | Zendy; Peterson Jr LeRoy | Zendy; Loye HansConrad zur | Zendy

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Tetrakis( N ‐ethyl‐9‐oxo‐4‐azonia‐5‐aza‐9 H ‐fluorene) tetra‐μ 3 ‐iodo‐hexa‐μ 2 ‐iodo‐dodecaiodohexabismuthate

Author(s) -

Tershansy Meredith A.,

Goforth Andrea M.,

Smith Mark D.,

Peterson Jr LeRoy,

Loye HansConrad zur

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806043960

Subject(s) - tetra , hexa , fluorene , chemistry , solvent , medicinal chemistry , ion , stereochemistry , organic chemistry , polymer

The new iodobismuthate compound (C 13 H 11 N 2 O) 4 [Bi 6 I 22 ] has been synthesized solvothermally by reacting BiI 3 , Zn(NO 3 ) 2 ·6H 2 O and 4,5‐diazafluoren‐9‐one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [ N ‐ethyl‐4,5‐dafo] + cations and one‐half of a centrosymmetric [Bi 6 I 22 ] 4− anion. The average terminal Bi—I, Bi—μ 2 ‐I and Bi—μ 3 ‐I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.

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