Open AccessNonacarbonyl(μ 2 ‐methanethiolato)(μ 3 ‐trimethylsilylacetylene)triruthenium
Author(s) -
Koentjoro Olivia F.,
Sparkes Hazel A.,
Raithby Paul R.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806038451
Subject(s) - perpendicular , chemistry , enhanced data rates for gsm evolution , group (periodic table) , crystallography , unit (ring theory) , geometry , computer science , mathematics , telecommunications , organic chemistry , mathematics education
The structure of the title compound, [Ru 3 (μ 2 CH 3 S){μ 3 ‐C 2 Si(CH 3 ) 3 }(CO) 9 ], contains an open triangle of Ru atoms. The open edge is bridged on one side by a μ 2 ‐S(CH 3 ) unit, and the other side of the triangle is capped by a [C[triple‐bond]CSi(CH 3 ) 3 ] group, with the acetylenic bond perpendicular to the open Ru⋯Ru edge.