Nonacarbonyl(μ 2 ‐methanethiolato)(μ 3 ‐trimethylsilylacetylene)triruthenium | Zendy

Koentjoro Olivia F. | Zendy; Sparkes Hazel A. | Zendy; Raithby Paul R. | Zendy

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Nonacarbonyl(μ 2 ‐methanethiolato)(μ 3 ‐trimethylsilylacetylene)triruthenium

Author(s) -

Koentjoro Olivia F.,

Sparkes Hazel A.,

Raithby Paul R.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806038451

Subject(s) - perpendicular , chemistry , enhanced data rates for gsm evolution , group (periodic table) , crystallography , unit (ring theory) , geometry , computer science , mathematics , telecommunications , organic chemistry , mathematics education

The structure of the title compound, [Ru 3 (μ 2 CH 3 S){μ 3 ‐C 2 Si(CH 3 ) 3 }(CO) 9 ], contains an open triangle of Ru atoms. The open edge is bridged on one side by a μ 2 ‐S(CH 3 ) unit, and the other side of the triangle is capped by a [C[triple‐bond]CSi(CH 3 ) 3 ] group, with the acetylenic bond perpendicular to the open Ru⋯Ru edge.

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