A 2:1 complex of 1,3‐bis(9 H ‐carbazol‐9‐yl)propane and tetrachloro‐ p ‐benzoquinone ( p ‐chloranil) | Zendy

Arslan Mustafa | Zendy; Asker Erol | Zendy; Krafcik Randolph B. | Zendy; Masnovi John | Zendy; Baker Ronald J. | Zendy

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A 2:1 complex of 1,3‐bis(9 H ‐carbazol‐9‐yl)propane and tetrachloro‐ p ‐benzoquinone ( p ‐chloranil)

Author(s) -

Arslan Mustafa,

Asker Erol,

Krafcik Randolph B.,

Masnovi John,

Baker Ronald J.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806031886

Subject(s) - chloranil , chemistry , crystallography , ring (chemistry) , benzene , propane , acceptor , stacking , carbazole , crystal (programming language) , crystal structure , photochemistry , physics , computer science , organic chemistry , programming language , condensed matter physics

In the title electron donor–acceptor complex, C 27 H 22 N 2 ·0.5C 6 Cl 4 O 2 , the p ‐chloranil molecule lies on a crystallographic inversion center, which is located at the center of the benzene ring. In the crystal structure, one p ‐chloranil molecule lies above and below the central rings of each donor group of two neighboring 1,3‐bis(9 H ‐carbazol‐9‐yl)propane molecules, with a ring‐centroid separation of 3.444 (1) Å. The angle between the planes of the stacking rings of the carbazole and p ‐chloranil molecules is 3.4 (2)°.

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