3‐Nitro‐1‐(triisopropylsilyl)‐1 H ‐pyrrole
Author(s) -
Kennedy Alan R.,
Khalaf Abedawn I.,
Suckling Colin J.,
Waigh Roger D.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806025943
Subject(s) - nitration , silylation , nitro , pyrrole , chemistry , cleavage (geology) , medicinal chemistry , hydrogen bond , organic chemistry , catalysis , molecule , materials science , alkyl , fracture (geology) , composite material
The nitration of 1‐(triisopropylsilyl)‐1 H ‐pyrrole leads to a mixture of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural determination showed the isolated products to be the title compound, C 13 H 24 N 2 2O 2 Si, and 2,4‐dinitropyrrole. In the solid state, the title compound exists as discrete molecules with only weak C—H⋯nitro hydrogen bonds between them.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom