Open Access3‐Nitro‐1‐(triisopropylsilyl)‐1 H ‐pyrrole
Author(s) -
Kennedy Alan R.,
Khalaf Abedawn I.,
Suckling Colin J.,
Waigh Roger D.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806025943
Subject(s) - nitration , silylation , nitro , pyrrole , chemistry , cleavage (geology) , medicinal chemistry , hydrogen bond , organic chemistry , catalysis , molecule , materials science , alkyl , fracture (geology) , composite material
The nitration of 1‐(triisopropylsilyl)‐1 H ‐pyrrole leads to a mixture of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural determination showed the isolated products to be the title compound, C 13 H 24 N 2 2O 2 Si, and 2,4‐dinitropyrrole. In the solid state, the title compound exists as discrete molecules with only weak C—H⋯nitro hydrogen bonds between them.