Octa‐ n ‐butylbis(μ 2 ‐4‐chloro‐3,5‐dinitrobenzoato‐κ 2  O : O ′)bis(4‐chloro‐3,5‐dinitrobenzoato‐κ O )di‐μ 3 ‐oxo‐tetratin(IV) | Zendy

Shahzadi Saira | Zendy; Ali Saqib | Zendy; Helliwell Madeleine | Zendy

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Octa‐ n ‐butylbis(μ 2 ‐4‐chloro‐3,5‐dinitrobenzoato‐κ 2 O : O ′)bis(4‐chloro‐3,5‐dinitrobenzoato‐κ O )di‐μ 3 ‐oxo‐tetratin(IV)

Author(s) -

Shahzadi Saira,

Ali Saqib,

Helliwell Madeleine

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806024627

Subject(s) - denticity , dimer , tin , crystallography , stereochemistry , chemistry , trigonal bipyramidal molecular geometry , atom (system on chip) , crystal structure , organic chemistry , computer science , embedded system

The title compound, [Sn 4 O 2 (C 7 H 2 ClN 2 O 6 ) 4 (C 4 H 9 ) 8 ], is a centrosymmetric dimer of an oxoditin(IV) complex. Two dibutylbis[4‐chloro‐3,5‐dinitrobenzoate]tin(IV) units containing monodentate and bridging bidentate carboxylate ligands are connected to the central Sn 2 O 2 core. Each Sn atom adopts a distorted trigonal–bipyramidal geometry, with Sn—C distances lying in the narrow range 2.119 (3)–2.135 (3) Å, while Sn—O distances range between 2.037 (2) and 2.286 (2) Å.

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