[η 2 ‐8‐( tert ‐Butylimino)‐1‐naphthyl]bis(η 5 ‐cyclopentadienyl)titanium(IV) | Zendy

Kooijman Huub | Zendy; Leijen Monique M. van | Zendy; Akkerman Otto S. | Zendy; Bickelhaupt Friedrich | Zendy; Spek Anthony L. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

[η 2 ‐8‐( tert ‐Butylimino)‐1‐naphthyl]bis(η 5 ‐cyclopentadienyl)titanium(IV)

Author(s) -

Kooijman Huub,

Leijen Monique M. van,

Akkerman Otto S.,

Bickelhaupt Friedrich,

Spek Anthony L.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806021726

Subject(s) - cyclopentadienyl complex , crystallography , molecule , tetrahedron , crystal (programming language) , atom (system on chip) , crystal structure , ion , titanium , chemistry , stereochemistry , physics , materials science , biochemistry , organic chemistry , computer science , embedded system , programming language , catalysis

The title compound, [Ti(C 5 H 5 ) 2 (C 15 H 15 N)], displays an iminoacyl fragment in an N‐outside conformation, indicating that the C=N vector points away from the σ‐bonded C atom. Considering only the geometrical centres of all η‐coordinated groups, the Ti IV ion adopts a severely distorted tetrahedral configuration. The crystal packing displays a short C—H⋯π contact linking the molecules into an infinite chain running along the b ‐axis direction.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research