Dicaesium pentacyanotricuprate(I), Cs 2 Cu 3 (CN) 5 | Zendy

Hibble Simon J. | Zendy; Pohl Alexander H. | Zendy; Bilbé Edward J. | Zendy; Chippindale Ann M. | Zendy

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Dicaesium pentacyanotricuprate(I), Cs 2 Cu 3 (CN) 5

Author(s) -

Hibble Simon J.,

Pohl Alexander H.,

Bilbé Edward J.,

Chippindale Ann M.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806020484

Subject(s) - cyanide , crystallography , triple bond , chemistry , materials science , stereochemistry , double bond , inorganic chemistry , polymer chemistry

Cs 2 Cu 3 (CN) 5 has a layered structure consisting of [Cu 3 (CN) 5 ] 2− sheets stacked in an ABAB fashion along the c axis, with Cs + cations lying between the sheets. The sheets are generated by linking –(CuCN)– chains, in which the C[triple‐bond]N groups are ordered, via [Cu(CN) 3 ] 2− units. The two bridging cyanide groups of each [Cu(CN) 3 ] 2− unit show partial `head‐to‐tail' disorder of C and N, whilst the third C[triple‐bond]N group is terminal and ordered with C bonded to Cu.

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