Tetrakis[3,5‐bis(trifluoromethyl)phenyl]silane | Zendy

Agnew Caroline | Zendy; Dillon Keith B. | Zendy; Goeta Andrés E. | Zendy; Thompson Amber L. | Zendy

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Tetrakis[3,5‐bis(trifluoromethyl)phenyl]silane

Author(s) -

Agnew Caroline,

Dillon Keith B.,

Goeta Andrés E.,

Thompson Amber L.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806017417

Subject(s) - silane , chemistry , trifluoromethyl , benzene , medicinal chemistry , tetra , bromide , silicon , meth , atom (system on chip) , organic chemistry , monomer , polymer , operating system , acrylate , computer science , alkyl

The title compound, tetrakis[3,5‐bis(trifluoromethyl)phenyl]silane (SiAr′′′ 4 , C 32 H 12 F 24 Si), is a minor product from the reaction of silicon(IV) bromide with lithiated 1,3‐bis(trifluoromethyl)benzene (Ar′H). The structure crystallizes with two half‐molecules in the asymmetric unit, with each central Si atom positioned on a twofold axis in a pseudo‐tetrahedral environment, with Si—C bond lengths in the range 1.873 (3)–1.879 (3) Å.

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