Open AccessTetrakis[3,5‐bis(trifluoromethyl)phenyl]silane
Author(s) -
Agnew Caroline,
Dillon Keith B.,
Goeta Andrés E.,
Thompson Amber L.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806017417
Subject(s) - silane , chemistry , trifluoromethyl , benzene , medicinal chemistry , tetra , bromide , silicon , meth , atom (system on chip) , organic chemistry , monomer , polymer , operating system , acrylate , computer science , alkyl
The title compound, tetrakis[3,5‐bis(trifluoromethyl)phenyl]silane (SiAr′′′ 4 , C 32 H 12 F 24 Si), is a minor product from the reaction of silicon(IV) bromide with lithiated 1,3‐bis(trifluoromethyl)benzene (Ar′H). The structure crystallizes with two half‐molecules in the asymmetric unit, with each central Si atom positioned on a twofold axis in a pseudo‐tetrahedral environment, with Si—C bond lengths in the range 1.873 (3)–1.879 (3) Å.