Poly[methyl­amine‐μ‐oxalato‐copper(II)] | Zendy

Keene Tony D. | Zendy; Hursthouse Michael B. | Zendy; Price Daniel J. | Zendy

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Poly[methylamine‐μ‐oxalato‐copper(II)]

Author(s) -

Keene Tony D.,

Hursthouse Michael B.,

Price Daniel J.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806016679

Subject(s) - oxalate , copper , methylamine , ion , crystallography , hydrogen bond , chemistry , amine gas treating , inorganic chemistry , molecule , organic chemistry

The six‐coordinate copper(II) ions in the title compound, [Cu(C 2 O 4 )(CH 5 N)], experience a Jahn–Teller distortion. The structure is a two‐dimensional coordination network, with three crystallographically independent oxalate ions, two of them centrosymmetric, bridging Cu II ions in three different coordination modes. Each Cu ion is also coordinated by methylamine which is involved in both intra‐ and interlayer hydrogen bonding.

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