The first molecular structure containing four hydroperoxo groups: piperazine‐2,3,5,6‐tetrayl tetrahydroperoxide pyrazine disolvate dihydrate | Zendy

Churakov Andrei V. | Zendy; Kuz'mina Lyudmila G. | Zendy; Prikhodchenko Petr V. | Zendy; Howard Judith A. K. | Zendy

Open Access

The first molecular structure containing four hydroperoxo groups: piperazine‐2,3,5,6‐tetrayl tetrahydroperoxide pyrazine disolvate dihydrate

Author(s) -

Churakov Andrei V.,

Kuz'mina Lyudmila G.,

Prikhodchenko Petr V.,

Howard Judith A. K.

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806016485

Subject(s) - pyrazine , piperazine , tetra , chemistry , hydrogen peroxide , crystal structure , hydrogen bond , medicinal chemistry , crystallography , stereochemistry , molecule , organic chemistry

The reaction of pyrazine with hydrogen peroxide resulted in piperazine‐2,3,5,6‐tetrayl tetrahydroperoxide, crystallizing as its pyrazine disolvate dihydrate, C 4 H 10 N 2 O 8 ·2C 4 H 4 N 2 ·2H 2 O. In the crystal structure, the tetraperoxo molecules, which possess a crystallographically imposed centre of symmetry, are linked into a three‐dimensional network by hydrogen‐bonding interactions involving the pyrazine and water molecules.

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