Open AccessDi‐μ‐pyridyl‐1:2κ 2 N : C 2 ;2:1κ 2 N : C 2 ‐μ‐tetrahydrofuran‐κ 2 O : O ‐bis[bromo(tetrahydrofuran)magnesium(II)] tetrahydrofuran hemisolvate
Author(s) -
Churakov Andrei V.,
Krut'ko Dmitry P.,
Borzov Maxim V.,
Kirsanov Roman S.,
Belov Sergei A.,
Howard Judith A. K.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806013742
Subject(s) - tetrahydrofuran , crystallography , molecule , chemistry , bipyramid , pentagonal bipyramidal molecular geometry , atom (system on chip) , trigonal bipyramidal molecular geometry , stereochemistry , crystal structure , organic chemistry , solvent , computer science , embedded system
The title compound, [Mg 2 Br 2 (C 5 H 4 N) 2 (C 4 H 8 O) 3 ]·0.5C 4 H 8 O, contains dimeric associations of Mg atoms bridged by tetrahydrofuran (THF) molecules. The coordination polyhedron of the Mg atom is a slightly distorted MgCNO 2 Br trigonal bipyramid with two THF molecules in the axial positions. One O atom occupies a site with symmetry 2.