Open Access(2‐Amidoethyl‐κ 2 C , O )trichloro(3‐chloropropionamide‐κ O )stannane
Author(s) -
Wardell James L.,
Tiekink Edward R. T.,
Wardell Solange M. S. V.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806010543
Subject(s) - ligand (biochemistry) , octahedron , chemistry , crystallography , chelation , atom (system on chip) , hydrogen bond , octahedral molecular geometry , stereochemistry , stannane , hydrogen atom , molecule , crystal structure , group (periodic table) , inorganic chemistry , biochemistry , receptor , organic chemistry , computer science , embedded system
The Sn atom in the title compound, [Sn(C 3 H 6 NO)Cl 3 (C 3 H 6 ClNO)], exists within a fac ‐CCl 3 O 2 donor set that defines an octahedral geometry and features a negatively charged chelating 2‐amidoethyl ligand as well as a neutral 3‐chloropropionamide ligand that coordinates exclusively via the carbonyl‐O atom. Extensive N—H⋯O and N—H⋯Cl hydrogen bonding leads to a layer structure.