Open Accessfac ‐Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl)rhodium(III) chloride/bromide dichloromethane benzene solvate
Author(s) -
Batsanov Andrei S.,
Marder Todd B.,
Seeler Fabian
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806005630
Subject(s) - bromide , dichloromethane , trimethylphosphine , chemistry , rhodium , chloride , benzene , ionic liquid , ion , medicinal chemistry , crystal structure , inorganic chemistry , organic chemistry , catalysis , solvent
The title complex, [RhCl 2 (C 4 H 11 P)(C 3 H 9 P) 3 ](Br 0.12 /Cl 0.88 )·CH 2 Cl 2 ·C 6 H 6 , has an ionic structure with fac ‐octahedral coordination of Rh III in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.
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