Open AccessAqua(dipicolinato‐κ 3 O , N , O ′)(1,10‐phenanthroline‐κ 2 N , N ′)zinc(II) monohydrate
Author(s) -
Harrison William T. A.,
Ramadevi Palani,
Kumaresan Sudalaiandi
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s160053680600420x
Subject(s) - isostructural , phenanthroline , chemistry , denticity , manganese , zinc , stacking , hydrogen bond , crystallography , crystal structure , molecule , organic chemistry
The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]·H 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10‐phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octahedral grouping. The crystal packing is consolidated by O—H⋯O hydrogen bonds and probable π–π stacking.