A tetraazamacrocycle with benzyl substituents | Zendy

Choi JongHa | Zendy; Clegg William | Zendy; Harrington Ross W. | Zendy; Yoon HyangMi | Zendy; Hong Yong Pyo | Zendy

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A tetraazamacrocycle with benzyl substituents

Author(s) -

Choi JongHa,

Clegg William,

Harrington Ross W.,

Yoon HyangMi,

Hong Yong Pyo

Publication year - 2006

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806001425

Subject(s) - hydrogen bond , chemistry , crystal structure , tetra , group (periodic table) , crystallography , crystal (programming language) , stereochemistry , medicinal chemistry , molecule , organic chemistry , computer science , programming language

The molecule of the title compound, 2,13‐dibenzyl‐5,16‐dimethyl‐2,6,13,17‐tetraazatricyclo[16.4.0 1,18 .0 7,12 ]docosane, C 34 H 52 N 4 , is centrosymmetric. The 14‐membered macrocycle adopts the stable trans ‐III ( RRSS ) configuration, with one benzyl group above and the other below the macrocycle mean plane. The crystal structure is stabilized by N—H⋯N hydrogen bonds. There is no intermolecular π–π interaction between benzyl planes, which are almost 6Å apart.

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