Dichloro(di‐2‐pyridylamine)zinc(II): a redetermination at 110 K | Zendy

Lutz Martin | Zendy; Spek Anthony L. | Zendy; Bruijnincx Pieter C. A. | Zendy; Klein Gebbink Robertus J. M. | Zendy; van Koten Gerard | Zendy

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Dichloro(di‐2‐pyridylamine)zinc(II): a redetermination at 110 K

Author(s) -

Lutz Martin,

Spek Anthony L.,

Bruijnincx Pieter C. A.,

Klein Gebbink Robertus J. M.,

van Koten Gerard

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805025973

Subject(s) - chemistry , zinc , amine gas treating , planar , atom (system on chip) , crystallography , medicinal chemistry , stereochemistry , organic chemistry , computer science , computer graphics (images) , embedded system

The title compound, [ZnCl 2 (C 10 H 9 N 3 )], has been investigated at 110 K. In contrast with the previously published room‐temperature structure [Ho et al. (1999). J. Chem. Soc. Dalton Trans. pp. 1581–1586], the amine N atom is found to have a symmetrical planar environment. The two independent Zn—Cl distances are significantly different, but the difference of 0.0414 (3) Å is within the range found in other tetrahedral ZnCl 2 complexes.

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