Thionordazepam: strong intermolecular N—H⋯N hydrogen‐bonded chains
Author(s) -
Narasegowda R. S.,
Vijay T.,
Yathirajan H. S.,
Nagaraja P.,
Narasimhamurthy T.,
Rathore R. S.
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805025286
Subject(s) - dihedral angle , ring (chemistry) , intermolecular force , hydrogen bond , crystallography , crystal (programming language) , chemistry , chain (unit) , crystal structure , molecule , physics , organic chemistry , astronomy , computer science , programming language
In the title compound, 7‐chloro‐1,3‐dihydro‐5‐phenyl‐2 H ‐1,4‐benzodiazepine‐2‐thione, C 15 H 11 ClN 2 S, the central seven‐membered diazepinethione ring adopts a boat conformation. The dihedral angle between the planes of the aromatic rings is 63.7 (1)°. The crystal packing is determined by strong N—H⋯N hydrogen bonds, generating a one‐dimensional chain along [001].
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