Tris(1,10‐phenanthroline)cobalt(II) triiodide
Author(s) -
Tershansy Meredith A.,
Goforth Andrea M.,
Smith Mark D.,
Peterson Jr LeRoy,
zur Loye HansConrad
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805023883
Subject(s) - triiodide , phenanthroline , tris , reagent , chemistry , cobalt , medicinal chemistry , combinatorial chemistry , inorganic chemistry , organic chemistry , biochemistry , electrode , dye sensitized solar cell , electrolyte
The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ](I 3 ) 2 , contains one [Co(1,10‐phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10‐phenanthroline, and SnI 2 , where the SnI 2 reagent serves only as a source of I atoms.
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