A binuclear iminodiacetato–copper(II) complex with the  N , N ′‐bis(pyridin‐4‐ylmethylene)hydrazine ligand as spacer | Zendy

Kundu Nabanita | Zendy; Chatterjee Pabitra Baran | Zendy; Chaudhury Muktimoy | Zendy; Tiekink Edward R. T. | Zendy

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A binuclear iminodiacetato–copper(II) complex with the N , N ′‐bis(pyridin‐4‐ylmethylene)hydrazine ligand as spacer

Author(s) -

Kundu Nabanita,

Chatterjee Pabitra Baran,

Chaudhury Muktimoy,

Tiekink Edward R. T.

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805021549

Subject(s) - hydrazine (antidepressant) , chemistry , denticity , copper , ene reaction , ligand (biochemistry) , hydrogen bond , crystal structure , hydrate , crystallography , medicinal chemistry , stereochemistry , molecule , organic chemistry , receptor , biochemistry , chromatography

The centrosymmetric title compound, μ‐ N , N ′‐bis(pyridin‐4‐ylmethylene)hydrazine‐bis[diaqua(iminodiacetato)copper(II)], [Cu 2 (C 4 H 5 NO 4 ) 2 (C 12 H 10 N 4 )(H 2 O) 4 ], features a trans ‐N 2 O 4 donor set that defines a heavily distorted octahedral geometry. Coordination is provided by a tridentate iminodiacetate (ida) dianion, one end of a bidentate bridging N , N ′‐bis(pyridin‐4‐ylmethylene)hydrazine ligand, which is disposed about a centre of inversion, and two water molecules. Extensive hydrogen bonding leads to a cohesive crystal structure.

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