Open Access1,3‐Bis(diphenylphosphino)propane‐2κ 2 P , P ′‐dicarbonyl‐1κ 2 C ‐chloro‐2κ Cl ‐{μ‐2,2′,2′′‐nitrilotriethanethiolato(3–)‐1κ 4 N , S , S ′, S ′′:2κ 2 S , S ′}iron(II)nickel(II) acetonitrile solvate
Author(s) -
Duff S. E.,
Hitchcock P. B.,
Davies S. C.,
Barclay J. E.,
Evans D. J.
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805018088
Subject(s) - chemistry , atom (system on chip) , propane , basal plane , ligand (biochemistry) , crystallography , solvent , stereochemistry , medicinal chemistry , receptor , organic chemistry , biochemistry , computer science , embedded system
The structure of the neutral title complex, [{Fe[(SCH 2 CH 2 ) 3 N](CO) 2 ‐ S , S ′}NiCl{[P(C 6 H 5 ) 2 ] 2 (CH 2 ) 3 }]·CH 3 CN or [FeNi(C 6 H 12 NS 3 )Cl(C 27 H 26 P 2 )(CO) 2 ]·C 2 H 3 N, is described. There are two independent complex molecules and two solvent molecules in the asymmetric unit. The Fe atoms are octahedrally coordinated; the three S atoms and a C atom of one of the two CO ligands form the equatorial plane, with the N atom of the (SCH 2 CH 2 ) 3 N ligand and the second carbonyl C atom lying in the axial positions. The Ni atoms are square pyramidally coordinated, with the two bridging S atoms and the P atoms of the 1,3‐bis(diphenylphosphino)propane ligand forming the basal plane and the Cl atom lying in the apical position.