Dichloro­tris(triphenyl­phosphine)ruthenium(II) dichloro­methane hemisolvate | Zendy

Cowley Andrew R. | Zendy; Dilworth Jonathan R. | Zendy; Maresca von Beckh W. Carlo A. | Zendy

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Dichlorotris(triphenylphosphine)ruthenium(II) dichloromethane hemisolvate

Author(s) -

Cowley Andrew R.,

Dilworth Jonathan R.,

Maresca von Beckh W. Carlo A.

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805016272

Subject(s) - triphenylphosphine , dichloromethane , ruthenium , ligand (biochemistry) , chemistry , coordination geometry , stereochemistry , molecule , receptor , organic chemistry , solvent , catalysis , biochemistry , hydrogen bond

A third modification of [RuCl 2 (PPh 3 ) 3 ] has been characterized, this time as the title compound, [RuCl 2 (C 18 H 15 P) 3 ]·0.5CH 2 Cl 2 . As seen for the previous modifications, the complex has a distorted square‐pyramidal geometry with an ortho ‐H atom `blocking' the site trans to the apical PPh 3 ligand. There is no evidence for a strong C—H⋯Ru interaction nor any specific directional force in the solid state.

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