Open AccessHigh‐spin [Fe(TTP)(THF) 2 ]
Author(s) -
Hu ChuanJiang,
Noll Bruce C.,
Scheidt W. Robert.
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805009633
Subject(s) - tetra , tetrahydrofuran , furan , chemistry , porphyrin , atom (system on chip) , medicinal chemistry , crystallography , stereochemistry , photochemistry , organic chemistry , solvent , computer science , embedded system
The title compound, bis(tetrahydrofuran)(5,10,15,20‐tetra‐ p ‐tolylporphyrinato)iron(II), [Fe(C 48 H 36 N 4 )(C 4 H 8 O) 2 ] or [Fe(TTP)(THF) 2 ] (TTP = dianion of meso ‐tetratolylporphyrin), is a six‐coordinate high‐spin iron(II) tetratolylporphyrin with two tetrahydrofuran molecules as axial ligands. The Fe II atom is at an inversion center. The average Fe—N distance is 2.067 (7) Å and the Fe—O distance is 2.3208 (8) Å.