(1 RS ,4 S  R ,8 S  R ,11 RS ,15 S  R ,18 RS ,22 RS ,25 S  R )‐1,4:8,11:15,18:22,25‐Tetraethano‐29 H ,31 H ‐tetrabenzo[ b,g,l,q ]porphine chloroform disolvate | Zendy

Aramaki Shinji | Zendy; Sakai Yoshimasa | Zendy; Yanagisawa Hiroyuki | Zendy; Senju Takatoshi | Zendy; Mizuguchi Jin | Zendy

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(1 RS ,4 S R ,8 S R ,11 RS ,15 S R ,18 RS ,22 RS ,25 S R )‐1,4:8,11:15,18:22,25‐Tetraethano‐29 H ,31 H ‐tetrabenzo[ b,g,l,q ]porphine chloroform disolvate

Author(s) -

Aramaki Shinji,

Sakai Yoshimasa,

Yanagisawa Hiroyuki,

Senju Takatoshi,

Mizuguchi Jin

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805004435

Subject(s) - porphyrin , skeleton (computer programming) , chemistry , crystallography , metal , stereochemistry , photochemistry , computer science , organic chemistry , programming language

In the title compound, C 44 H 38 N 4 ·2CHCl 3 , the porphine (CP) is a soluble precursor of metal‐free porphyrin which exhibits an excellent field‐effect transistor characteristic. The CP skeleton is entirely flat and characterized by crystallographic C i symmetry. In the present geometrical isomer, the C—C single‐bond linkages of the four peripheries are arranged in an above–above–below–below manner with respect to the CP skeleton.

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