1,4:8,11:15,18:22,25‐Tetraethano‐29 H ,31 H ‐tetrabenzo[ b , g , l , q ]porphine toluene trisolvate | Zendy

Aramaki Shinji | Zendy; Sakai Yoshimasa | Zendy; Yanagisawa Hiroyuki | Zendy; Mizuguchi Jin | Zendy

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1,4:8,11:15,18:22,25‐Tetraethano‐29 H ,31 H ‐tetrabenzo[ b , g , l , q ]porphine toluene trisolvate

Author(s) -

Aramaki Shinji,

Sakai Yoshimasa,

Yanagisawa Hiroyuki,

Mizuguchi Jin

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805004228

Subject(s) - porphyrin , toluene , crystallography , symmetry (geometry) , chemistry , crystal (programming language) , metal , field (mathematics) , crystal structure , stereochemistry , photochemistry , geometry , mathematics , organic chemistry , computer science , pure mathematics , programming language

In the title compound, C 44 H 38 N 4 ·3C 7 H 8 , the porphine (CP) is a soluble precursor of metal‐free porphyrin which exhibits an excellent field‐effect transistor characteristic. The CP molecule is not entirely flat in its crystal structure ( i.e. not D 2 h ), but is slightly deformed, as characterized by crystallographic C i symmetry. The geometric isomer of CP could not be identified due to orientational disorder.

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