Diaquabis(1,1,4‐trimethylthiosemicarbazide)nickel(II) dinitrate | Zendy

Burrows Andrew D. | Zendy; Harrington Ross W. | Zendy; Mahon Mary F. | Zendy

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Diaquabis(1,1,4‐trimethylthiosemicarbazide)nickel(II) dinitrate

Author(s) -

Burrows Andrew D.,

Harrington Ross W.,

Mahon Mary F.

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536805002965

Subject(s) - semicarbazide , chemistry , nickel , hydrogen bond , thio , octahedron , octahedral molecular geometry , crystallography , crystal structure , nitrate , inorganic chemistry , stereochemistry , molecule , organic chemistry

The determination of the crystal structure of the title compound, [Ni(C 4 H 11 N 3 S) 2 (H 2 O) 2 ](NO 3 ) 2 , reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4‐trimethylthiosemicarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.

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