Open AccessDiaquabis(1,1,4‐trimethylthiosemicarbazide)nickel(II) dinitrate
Author(s) -
Burrows Andrew D.,
Harrington Ross W.,
Mahon Mary F.
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805002965
Subject(s) - semicarbazide , chemistry , nickel , hydrogen bond , thio , octahedron , octahedral molecular geometry , crystallography , crystal structure , nitrate , inorganic chemistry , stereochemistry , molecule , organic chemistry
The determination of the crystal structure of the title compound, [Ni(C 4 H 11 N 3 S) 2 (H 2 O) 2 ](NO 3 ) 2 , reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4‐trimethylthiosemicarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.