
[1‐(3‐Aminopropyl)‐4,7‐dithia‐1‐azacyclononane‐κ 4 N , N ′, S,S ′]bis(dimethylformamide‐κ O )nickel(II) bis(tetraphenylborate) acetonitrile disolvate
Author(s) -
Lippolis Vito,
Blake Alexander J.
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804033380
Subject(s) - tetraphenylborate , chemistry , acetonitrile , nickel , dimethylformamide , medicinal chemistry , inorganic chemistry , organic chemistry , ion , solvent
In the title complex, [Ni(C 3 H 7 NO) 2 (C 9 H 20 N 2 S 2 )](C 24 H 20 B) 2 ·2CH 3 CN, the metal centre has a distorted octahedral environment, with four coordination sites occupied by two N‐ and two S‐donor atoms from a 3‐aminopropyl pendant arm derivative of the nine‐membered macrocycle 1‐aza‐4,7‐dithiacyclononane, and the remaining two positions by two mutually cis dimethylformamide ligands.