Open AccessChloro{1‐[(dimethylamino)methyl‐κ N ]‐1 H ‐indolyl‐κ C 2 }(triphenylphosphine‐κ P )palladium(II) dichloromethane solvate
Author(s) -
Cooper Richard I.,
Cowley Andrew R.,
Capito Elena,
Brown John M.,
Ricci Alfredo
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804033227
Subject(s) - substituent , dichloromethane , triphenylphosphine , palladium , ring (chemistry) , chemistry , medicinal chemistry , methane , stereochemistry , organic chemistry , catalysis , solvent
The title compound, [Pd(C 11 H 13 N 2 )Cl(C 18 H 15 P)]·CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N ‐substituent in five‐membered ring heterocycles [Nonoyama & Nakajima (1998). Polyhedron 18 , 533–543.].