Open AccessAcetato[1‐(oxazolin‐2‐ylmethyl‐κ N )‐1 H ‐indolyl‐κ C 2 ](triphenylphosphine)palladium(II) dichloromethane solvate
Author(s) -
Cowley Andrew R.,
Cooper Richard I.,
Capito Elena,
Brown John M,
Ricci Alfredo
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804032891
Subject(s) - dichloromethane , triphenylphosphine , substituent , palladium , ring (chemistry) , chemistry , medicinal chemistry , methane , stereochemistry , organic chemistry , catalysis , solvent
The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]·CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N ‐substituent in five‐membered‐ring heterocycles [Nonoyama & Nakajima (1998). Polyhedron , 18 , 533–543].