Sm 2 NaIrO 6 , a monoclinically distorted double perovskite | Zendy

Mugavero III Samuel J. | Zendy; Puzdrjakova Irina V. | Zendy; Smith Mark D. | Zendy; Loye HansConrad zur | Zendy

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Sm 2 NaIrO 6 , a monoclinically distorted double perovskite

Author(s) -

Mugavero III Samuel J.,

Puzdrjakova Irina V.,

Smith Mark D.,

Loye HansConrad zur

Publication year - 2005

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804031836

Subject(s) - octahedron , monoclinic crystal system , crystallography , lanthanide , samarium , iridium , materials science , perovskite (structure) , crystal structure , group (periodic table) , lattice (music) , chemistry , inorganic chemistry , physics , ion , catalysis , biochemistry , organic chemistry , acoustics

Single crystals of the lanthanide‐containing iridate, disamarium sodium iridium hexaoxide, Sm 2 NaIrO 6 , were prepared via high‐temperature flux growth and structurally characterized by single‐crystal X‐ray diffraction. The compound crystallizes in the monoclinic space group P 2 1 / n and is a double perovskite, consisting of a 1:1 ordered rock‐salt‐type lattice of corner‐shared NaO 6 and IrO 6 distorted octahedra. Samarium occupies the eightfold coordination site generated by the connectivity of the octahedra.

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