Bis­(tetra‐ n ‐butyl­ammonium) tetrakis­[chloro(μ 3 ‐sulfido)copper(I)]­tungstate(VI): a second polymorph | Zendy

Hossaini Sadr Moayad | Zendy; Seyed Ahmadian Seyed Masoud | Zendy; Brooks Neil R. | Zendy; Clegg William | Zendy

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Bis(tetra‐ n ‐butylammonium) tetrakis[chloro(μ 3 ‐sulfido)copper(I)]tungstate(VI): a second polymorph

Author(s) -

Hossaini Sadr Moayad,

Seyed Ahmadian Seyed Masoud,

Brooks Neil R.,

Clegg William

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804030582

Subject(s) - tungstate , crystallography , tetrahedron , copper , ion , chemistry , tetra , atom (system on chip) , planar , octahedron , symmetry (geometry) , trigonal crystal system , crystal structure , inorganic chemistry , mathematics , geometry , medicinal chemistry , computer graphics (images) , organic chemistry , computer science , embedded system

The title compound, (C 16 H 36 N) 2 [WS 4 (CuCl) 4 ], has been obtained in a second polymorphic form. The anion, in which four of the six S⋯S edges of the central WS 4 tetrahedron are bridged by CuCl neutral molecular units to give a planar pentanuclear WCu 4 framework, is disordered on a crystallographic fourfold rotation axis, requiring equal occupancy of two sets of four positions for the S atoms. Copper has distorted trigonal planar coordination, involving two μ 3 ‐S atoms and a terminal Cl atom. The two independent cations lie on positions of symmetry .

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