Open AccessDichlorobis(triphenylphosphine oxide‐κ O )nickel(II)
Author(s) -
MorenoFuquen Rodolfo,
Cifuentes Olga,
Naranjo Jaime Valderrama,
Serratto Luis Manuel,
Kennedy Alan R.
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804029125
Subject(s) - isostructural , nickel , triphenylphosphine , atom (system on chip) , tetrahedron , crystallography , copper , chemistry , oxide , triphenylphosphine oxide , nickel oxide , coordination geometry , crystal structure , molecule , catalysis , organic chemistry , computer science , hydrogen bond , embedded system
The title nickel(II) complex, [NiCl 2 (C 18 H 15 OP) 2 ], was prepared in order to determine the coordination of the Ni atom. The Ni atom lies on a twofold axis and is four‐coordinated by two Cl atoms and two O atoms in a distorted tetrahedral coordination geometry. The Ni—Cl and Ni—O distances are 2.2151 (6) and 1.9662 (16) Å, respectively. The title compound is compared with the four‐coordinated copper(II) analog; the two systems are isostructural.