Open Access{4,4′‐Di‐ tert ‐butyl‐6,6′‐bis(dimethoxymethyl)‐2,2′‐[propane‐1,3‐diylbis(nitrilomethylidyne)]bis(thiophenolato)‐κ 4 S,N,N ′, S ′}nickel(II)
Author(s) -
Bjernemose Jens K.,
McKenzie Christine J.,
Raithby Paul R.,
Teat Simon J.
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804028879
Subject(s) - nickel , propane , nickel compounds , metal , planar , chemistry , square (algebra) , crystallography , medicinal chemistry , physics , stereochemistry , geometry , mathematics , organic chemistry , computer graphics (images) , computer science
The title compound, [Ni(C 31 H 44 N 2 O 4 S 2 )], is an N 2 S 2 four‐coordinated nickel(II) complex. The coordination geometry of the metal, on a twofold rotation axis, is more distorted from square planar than in related compounds.