A mixed‐halogen tricarbonylmanganese(I) complex:  fac ‐[MnBr 0.3 Cl 0.7 {Ph 2 P(CH 2 ) 3 PPh 2 }(CO) 3 ] | Zendy

Light Mark E. | Zendy; Hursthouse Michael B. | Zendy; Beckett Michael A. | Zendy; Brassington David S. | Zendy

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A mixed‐halogen tricarbonylmanganese(I) complex: fac ‐[MnBr 0.3 Cl 0.7 {Ph 2 P(CH 2 ) 3 PPh 2 }(CO) 3 ]

Author(s) -

Light Mark E.,

Hursthouse Michael B.,

Beckett Michael A.,

Brassington David S.

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804019385

Subject(s) - halogen , manganese , recrystallization (geology) , crystallography , propane , hexane , bond length , materials science , chemistry , crystal structure , metallurgy , organic chemistry , alkyl , paleontology , biology

Crystals of the mixed halogen complex, fac ‐(bromo/chloro)tricarbonyl[1,3‐bis(diphenylphosphino)propane]manganese(I), fac ‐[MnBr 0.3 Cl 0.7 (C 30 H 26 O 3 P 2 )(CO) 3 ], were obtained from a prolonged recrystallization attempt of [MnBr{Ph 2 P(CH 2 ) 3 PPh 2 }(CO) 3 ] from CHCl 3 /hexane solution at 263 K. Common coordinates are found for all but the halogen atoms in the disordered structure, but the Mn— X vectors differ by 3.5 (5)° and the M — X bond lengths differ by 0.10 (1) Å.

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