Open Access[ N,N ′‐Bis‐( o ‐sulfidobenzylidene)‐1,3‐diaminopropane]nickel(II) 1,4‐dioxane solvate
Author(s) -
Taylor Michelle K.,
Reglinski John,
Wallace Dawn
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804011882
Subject(s) - nickel , propane , schiff base , benzene , chemistry , medicinal chemistry , crystallography , stereochemistry , organic chemistry
The title tetradentate Schiff base complex (systematic name: {2,2′‐[propane‐1,3‐diylbis(nitrilomethylidyne)]benzenethiolato‐κ 4 S , N,N ′, S ′}nickel(II) 1,4‐dioxane solvate), [Ni(C 17 H 16 N 2 S 2 )]·C 4 H 8 O 2 , contains an Ni atom coordinated within a tetrahedrally distorted planar N 2 S 2 environment, with average Ni—N and Ni—S bond lengths of 1.922 (1) and 2.167 (1) Å, respectively.