Hydrogen bonding in thiacrown complexes: chlorobis(nicotinamide‐κ N )(1,4,7‐trithiacyclononane‐κ 3  S )ruthenium(II) hexafluorophosphate monohydrate | Zendy

Adams Harry | Zendy; Shan N. | Zendy; Thomas J. | Zendy

Open Access

Hydrogen bonding in thiacrown complexes: chlorobis(nicotinamide‐κ N )(1,4,7‐trithiacyclononane‐κ 3 S )ruthenium(II) hexafluorophosphate monohydrate

Author(s) -

Adams Harry,

Shan N.,

Thomas J.

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804009602

Subject(s) - chemistry , ruthenium , hexa , hydrogen bond , amide , hexafluorophosphate , aqueous solution , medicinal chemistry , nonane , nicotinamide , polymer chemistry , stereochemistry , molecule , organic chemistry , catalysis , enzyme , ionic liquid

The title complex, [RuCl L 2 ([9]‐ane‐S 3 )]PF 6 ·H 2 O [where L is nicotinamide, C 7 H 6 N 2 O) and [9]‐ane‐S 3 is 1,4,7‐trithiacyclononane (C 6 H 12 S 3 )], was isolated as a hexafluorophosphate salt from water–ethanol. The structure confirms that the amide moieties are available for possible mutual hydrogen‐bond interactions. However, from aqueous solvents, these sites are involved in networks of interactions with water molecules.

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