Open AccessHydrogen bonding in thiacrown complexes: chlorobis(nicotinamide‐κ N )(1,4,7‐trithiacyclononane‐κ 3 S )ruthenium(II) hexafluorophosphate monohydrate
Author(s) -
Adams Harry,
Shan N.,
Thomas J.
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804009602
Subject(s) - chemistry , ruthenium , hexa , hydrogen bond , amide , hexafluorophosphate , aqueous solution , medicinal chemistry , nonane , nicotinamide , polymer chemistry , stereochemistry , molecule , organic chemistry , catalysis , enzyme , ionic liquid
The title complex, [RuCl L 2 ([9]‐ane‐S 3 )]PF 6 ·H 2 O [where L is nicotinamide, C 7 H 6 N 2 O) and [9]‐ane‐S 3 is 1,4,7‐trithiacyclononane (C 6 H 12 S 3 )], was isolated as a hexafluorophosphate salt from water–ethanol. The structure confirms that the amide moieties are available for possible mutual hydrogen‐bond interactions. However, from aqueous solvents, these sites are involved in networks of interactions with water molecules.