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Di­cyclo­hexyl­aminium 4‐nitro­anthranilate
Author(s) -
Smith Graham,
Wermuth Urs D.,
Healy Peter C.
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536804006981
Subject(s) - amine gas treating , hydrogen bond , nitro , intramolecular force , chemistry , protonation , acceptor , group (periodic table) , stereochemistry , crystal structure , medicinal chemistry , crystallography , molecule , organic chemistry , ion , alkyl , physics , condensed matter physics
The crystal structure of di­cyclo­hexyl­amnium 4‐nitro­anthra­nilate, C 12 H 24 N + ·C 7 H 5 N 2 O 4 − , shows a three‐dimensional hydrogen‐bonded network polymer in which the protonated amine groups of both of the independent mol­ecules of di­cyclo­hexyl­amine give similar hydrogen‐bonding interactions with oxy­gen acceptors of four separate anthranilate carboxyl­ate groups [N⋯O = 2.730 (3)–2.782 (2) Å]. Secondary centrosymmetric peripheral hydrogen‐bonding linkages involve the amine groups of the anthranilate anions with nitro and carboxyl­ate O‐atom acceptors, while these groups are also involved in intramolecular N—H⋯O(carboxyl­ate) associations [2.663 (3) and 2.679 (3) Å].

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