Open AccessOctabenzyldichlorodi‐μ 2 ‐hydroxo‐di‐μ 3 ‐oxo‐tetratin toluene disolvate
Author(s) -
Mohamed E. Mothi,
Panchanatheswaran Krishnaswamy,
Low John N.,
Glidewell Christopher
Publication year - 2004
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s160053680400697x
Subject(s) - toluene , stoichiometry , dimer , crystallography , molecule , chemistry , bipyramid , tin , trigonal bipyramidal molecular geometry , tetragonal crystal system , planar , trigonal crystal system , stereochemistry , inorganic chemistry , crystal structure , organic chemistry , computer graphics (images) , computer science
The title tin complex crystallizes as a stoichiometric toluene‐solvated dimer of 1,1,3,3‐tetrabenzyl‐1‐chloro‐3‐hydroxydistannoxane, [Sn 4 (C 7 H 7 ) 8 Cl 2 O 2 (OH) 2 ]·2C 7 H 8 . The tetranuclear molecule lies across a centre of inversion in space group P 2 1 / n ; the Sn 4 O 4 framework, in which the two independent Sn centres both have distorted trigonal bipyramidal coordination, is essentially planar.