(Chloromethyl)trimethylsilane at 160 K | Zendy

Fraser Stewart | Zendy; Parsons Simon | Zendy

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(Chloromethyl)trimethylsilane at 160 K

Author(s) -

Fraser Stewart,

Parsons Simon

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804005276

Subject(s) - trimethylsilane , silane , steric effects , methyl group , chemistry , group (periodic table) , atom (system on chip) , crystallography , stereochemistry , medicinal chemistry , organic chemistry , computer science , embedded system

(Chloromethyl)trimethylsilane, Me 3 SiCH 2 Cl or C 4 H 11 ClSi, is a liquid at room temperature, and it was crystallized using in situ methods. The C—Si—C bond angles involving the chloromethyl group are somewhat smaller than those involving only methyl groups [105.5 (2)–109.47 (19)° versus 110.01 (19)–111.2 (2)°], which is ascribable to both the electronegative and the steric effects of the Cl atom.

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