Tetra‐ n ‐butylamine(carbonato‐κ 2  O , O ′)cobalt(III)  n ‐butylcarbamate dihydrate | Zendy

Keene Tony D. | Zendy; Hursthouse Michael B. | Zendy; Price Daniel J. | Zendy

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Tetra‐ n ‐butylamine(carbonato‐κ 2 O , O ′)cobalt(III) n ‐butylcarbamate dihydrate

Author(s) -

Keene Tony D.,

Hursthouse Michael B.,

Price Daniel J.

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536804005070

Subject(s) - cobalt , coordination sphere , octahedron , tetra , carbonate , crystallography , amine gas treating , chemistry , crystallization , chelation , octahedral molecular geometry , crystal structure , inorganic chemistry , medicinal chemistry , organic chemistry

The title compound, [Co(CO 3 )(C 4 H 11 N) 4 ](C 5 H 10 NO 2 )·2H 2 O, is a coordination complex with an N 4 O 2 coordination sphere around the central Co III ion. The small bite angle of the chelating carbonate causes a distortion of the octahedral geometry to an approximately C 2 v local symmetry. Hydrogen‐bonding between the carbonate, carbamate and amine groups, and the water of crystallization, results in a complex two‐dimensional network.

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