[Tris(2‐aminoethyl)amine]manganese(II) heptasulfidotetraantimony(III) hemihydrate | Zendy

Schaefer Michael | Zendy; Kurowski Daniel | Zendy; Pfitzner Arno | Zendy; Näther Christian | Zendy; Bensch Wolfgang | Zendy

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[Tris(2‐aminoethyl)amine]manganese(II) heptasulfidotetraantimony(III) hemihydrate

Author(s) -

Schaefer Michael,

Kurowski Daniel,

Pfitzner Arno,

Näther Christian,

Bensch Wolfgang

Publication year - 2004

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536803027983

Subject(s) - amine gas treating , manganese , hemihydrate , chemistry , octahedron , tris , ion , crystallography , medicinal chemistry , inorganic chemistry , organic chemistry , materials science , metallurgy , biochemistry , gypsum

Yellow crystals of the title compound, [Mn(dien) 2 ][Sb 4 S 7 ]·0.5H 2 O (dien = diethylenetriamine = C 4 H 13 N 3 ) were synthesized under solvothermal conditions by reacting MnSb 2 S 4 with pure dien. The Mn 2+ ion is in an octahedral environment of six N atoms of the tridentate dien molecules. The [Sb 4 S 7 ] 2− units, and anions are joined together to form two‐dimensional layers. In the layered anion, Sb 2 S 2 , Sb 4 S 4 and Sb 8 S 8 hetero‐rings are found.

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