Bromo[(diphenylphosphino‐κ P )(diphenylphosphinoyl)methane]gold(I) acetonitrile solvate | Zendy

Williams Michael L. | Zendy; Boyd Sue E. | Zendy; Dunstan Samuel P. C. | Zendy; Slade Deborah L. | Zendy; Healy Peter C. | Zendy

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Bromo[(diphenylphosphino‐κ P )(diphenylphosphinoyl)methane]gold(I) acetonitrile solvate

Author(s) -

Williams Michael L.,

Boyd Sue E.,

Dunstan Samuel P. C.,

Slade Deborah L.,

Healy Peter C.

Publication year - 2003

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536803017732

Subject(s) - intramolecular force , acetonitrile , chemistry , methane , medicinal chemistry , ligand (biochemistry) , stereochemistry , bond length , crystallography , receptor , organic chemistry , crystal structure , biochemistry

In the title compound, [AuBr(dppmO)]·CH 3 CN [dppmO = Ph 2 P(CH 2 )P(O)Ph 2 ], the dppmO ligand coordinates through the P donor to give a linear two‐coordinate P—Au—Br gold(I) complex. The Au—Br and Au—P bond lengths are 2.241 (2) and 2.4069 (19) Å, respectively. The P—Au—Br and P=O groups lie almost parallel to each other [O—P⋯P—Au = 8.3 (2)°], while the intramolecular Au⋯O distance is 3.274 (4) Å.

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