Hydronium pentaaquacopper(II) triperchlorate | Zendy

Bramsen Fabienne | Zendy; Bond Andrew D. | Zendy; McKenzie Christine J. | Zendy

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Hydronium pentaaquacopper(II) triperchlorate

Author(s) -

Bramsen Fabienne,

Bond Andrew D.,

McKenzie Christine J.

Publication year - 2003

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536803014272

Subject(s) - moiety , perchlorate , chemistry , crystallography , hydronium , ion , crystal structure , copper , salt (chemistry) , stereochemistry , square pyramidal molecular geometry , crystal (programming language) , inorganic chemistry , organic chemistry , computer science , programming language

The crystal structure of the double salt hydronium pentaaquacopper(II) triperchlorate, (H 3 O)[Cu(H 2 O) 5 ](ClO 4 ) 3 , has been determined at 180 K. In space group P 3 2 21, the structure contains a square‐pyramidal [Cu(H 2 O) 5 ] 2+ moiety with its basal plane capped by one edge of a perchlorate anion, so that Cu II exhibits [5+2] coordination. Both cations and one of the anions lie on twofold rotation axes.

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