Ethylenediammonium aquabis(malonato)oxovanadate(IV) | Zendy

Kaludjerović Goran N. | Zendy; Heinemann Frank W. | Zendy; Leovac Vukadin M. | Zendy; Trifunović Srećko R. | Zendy; Sabo Tibor J. | Zendy

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Ethylenediammonium aquabis(malonato)oxovanadate(IV)

Author(s) -

Kaludjerović Goran N.,

Heinemann Frank W.,

Leovac Vukadin M.,

Trifunović Srećko R.,

Sabo Tibor J.

Publication year - 2003

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s160053680301417x

Subject(s) - malonate , crystallography , ligand (biochemistry) , chemistry , vanadium , ion , carboxylate , symmetry (geometry) , atom (system on chip) , stereochemistry , inorganic chemistry , geometry , receptor , computer science , biochemistry , mathematics , organic chemistry , embedded system

In the anion of the title compound, (C 2 H 10 N 2 )[VO(H 2 O)(C 3 H 2 O 4 ) 2 ] or H 2 en[VO(mal) 2 H 2 O], vanadium(IV) is distorted‐octahedrally coordinated by six donor O atoms. The two malonate ligands are situated in the equatorial plane, whereas the oxo and the water ligand occupy axial positions. The apical V=O bond exhibits a strong trans influence. The anion possesses crystallographically imposed C 2 symmetry, with the central V atom, the oxo and the water ligand lying on the twofold axis.

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