A potassium crown ether complex with dichloroaurate(I) | Zendy

Hossain Md. Alamgir | Zendy; Powell Douglas R. | Zendy; BowmanJames Kristin | Zendy

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A potassium crown ether complex with dichloroaurate(I)

Author(s) -

Hossain Md. Alamgir,

Powell Douglas R.,

BowmanJames Kristin

Publication year - 2003

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536803000813

Subject(s) - potassium , octane , crown ether , chemistry , ring (chemistry) , crystallography , ether , symmetry (geometry) , ion , stereochemistry , medicinal chemistry , organic chemistry , geometry , mathematics

The title compound, (1,4,7,10,13,16‐hexaoxacyclooctane)potassium dichloroaurate(I), [K(C 12 H 24 O 6 )][AuCl 2 ], consists of potassium ion encapsulated by the 18‐membered crown ether 1,4,7,10,13,16‐hexaoxacyclooctane and a linear dichloroaurate(I) monoanion. The potassium occupies a crystallographic center of symmetry with a ring coordination number of six, and two chlorides in axial sites at a distance of 3.2306 (5) Å. The linear anionic species sits on another crystallographic center of symmetry.

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