Hydrazine carbodithioic acid pyridinium‐2‐yl methyl ester chloride | Zendy

Crouse Karen A. | Zendy; Chew Kar Teng | Zendy; Yamin Bohari M. | Zendy; Ng Seik Weng | Zendy; Tarafder M. T. H. | Zendy

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Hydrazine carbodithioic acid pyridinium‐2‐yl methyl ester chloride

Author(s) -

Crouse Karen A.,

Chew Kar Teng,

Yamin Bohari M.,

Ng Seik Weng,

Tarafder M. T. H.

Publication year - 2003

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s160053680300014x

Subject(s) - moiety , chemistry , hydrogen bond , intramolecular force , double bond , pyridine , pyridinium , ring (chemistry) , hydrazine (antidepressant) , medicinal chemistry , protonation , chloride , ionic bonding , thio , stereochemistry , polymer chemistry , ion , organic chemistry , molecule , chromatography

The title compound, [C 7 H 10 N 3 S 2 ] + ·Cl − , exists as an ionic compound of a dithiocarbazate system, with a zwitterionic + H 3 NNCS − moiety and a protonated pyridine ring. The C—S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C—N of the carbazate moiety has double‐bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two‐dimensional network perpendicular to b .

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