A 2:1 cocrystal of 6,13‐dihydropentacene and pentacene
Author(s) -
Mattheus Christine C.,
Baas Jacob,
Meetsma Auke,
Boer Jan L. de,
Kloc Christian,
Siegrist Theo,
Palstra Thomas T. M.
Publication year - 2002
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536802018445
Subject(s) - pentacene , monoclinic crystal system , cocrystal , materials science , crystallography , chemistry , crystal structure , nanotechnology , organic chemistry , molecule , thin film transistor , hydrogen bond , layer (electronics)
6,13‐Dihydropentacene and pentacene cocrystallize in a ratio of 2:1, i.e . C 22 H 16 ·0.5C 22 H 14 , during vapour transport of commercial pentacene in a gas flow. The crystal structure is monoclinic, space group P 2 1 / n , and contains one dihydropentacene molecule and half a pentacene molecule in the asymmetric unit.
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