Accurate Redeterminations of 1,1'‐Dibenzoylferrocene and (4‐Nitrophenyl)ferrocene | Zendy

Gallagher J. F. | Zendy; Ferguson G. | Zendy; Ahmed S. Z. | Zendy; Glidewell C. | Zendy; Lewis A. | Zendy

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Accurate Redeterminations of 1,1'‐Dibenzoylferrocene and (4‐Nitrophenyl)ferrocene

Author(s) -

Gallagher J. F.,

Ferguson G.,

Ahmed S. Z.,

Glidewell C.,

Lewis A.

Publication year - 1997

Publication title -

acta crystallographica section c

Language(s) - English

Resource type - Journals

eISSN - 1600-5759

pISSN - 0108-2701

DOI - 10.1107/s0108270197012602

Subject(s) - ferrocene , cyclopentadienyl complex , van der waals force , molecule , hydrogen bond , chemistry , solid state , crystallography , metallocene , stereochemistry , organic chemistry , polymerization , polymer , electrochemistry , catalysis , electrode

In the solid state, molecules of 1,1'-dibenzoylferrocene, [Fe(C₁₂H₉O)₂], (I), are linked to form infinite chains in the [100] direction via (cyclopentadienyl)C-H...O hydrogen bonds [C...O 3.354 (4) Å]. In the structure of (4-nitrophenyl)ferrocene, [Fe(C₅H₅)(C₁₁H₈NO₂)], (II), there are no C-H...O hydrogen bonds and molecules are separated by normal van der Waals distances. For earlier determinations see Struchkov [Dokl. Akad. Nauk SSSR (1956), 110, 67-70] for (I) and Roberts et al. [J. Chem. Soc. Dalton Trans. (1988), pp. 1549-1556] for (II)

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