Open Access(2,2'‐Bipyridyl‐ N , N ')dibromopalladium(II)
Author(s) -
Smeets W. J. J.,
Spek A. L.,
Hoare J. L.,
Canty A. J.,
Hovestad N.,
Van Koten G.
Publication year - 1997
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270197004149
Subject(s) - dihedral angle , stack (abstract data type) , planar , crystallography , square (algebra) , pyridine , chain (unit) , plane (geometry) , dihedral group , chemistry , mathematics , geometry , group (periodic table) , physics , molecule , computer science , hydrogen bond , computer graphics (images) , medicinal chemistry , programming language , astronomy , organic chemistry
The title comlex, PdCl2(bipy), the 2,2'-bipyridine complex of palladium dichloride, has square-planar geometry for palladium with Pd-N 2.047(5) and Pd-Br 2.4102(9) Angstroms. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3) degrees with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41(1) A and a Pd··Pd separation of 5.246(1) A to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2'-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy)
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom