Open AccessOn the structure of the mixed ligand complex of [VO] 2+ with hydrotris(3,5‐dimethylpyrazolyl)borato and 1,3‐diphenyl‐1,3‐propanedionato ligands
Author(s) -
Marsh R. E.
Publication year - 1994
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270194004154
Subject(s) - ligand (biochemistry) , chemistry , stereochemistry , biochemistry , receptor
The structure of (1,3-diphenyl-1,3-propanedionato-kappa2O,O')oxo[tris(3,5-dimethyl-1-pyrazolyl-kappaN2)hydroborato]vanadium(IV) methyl cyanide, [VO(C15H22BN6)(C15H11O2)].xCH3CN, has recently been described and refined [Beddoes, Eardley, Mabbs, Moorcroft & Passand (1993). Acta Cryst. C49, 1923-1926] in space group Pna2(1) (orthorhombic; a = 15.960 (1), b = 12.447 (1), c = 17.044 (1) angstrom, Z = 4). It is better described in Pnma (conventional setting of Pnam). Revised coordinates are given and the anomalous bond lengths reported earlier are revised.