Open Access1‐(Isopropylideneamino)guanidinium 2‐nitrobenzoate: formation of corrugated sheets from R 2 2 (8) and R 6 4 (16) rings
Author(s) -
Skakle Janet M. S.,
Wardell James L.,
Wardell Solange M. S. V.
Publication year - 2006
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270106020580
Subject(s) - hydrogen bond , guanidine , chemistry , group (periodic table) , crystallography , nitro , hydrogen , stereochemistry , molecule , organic chemistry , alkyl
In the title compound, C 4 H 11 N 4 + ·C 7 H 4 NO 4 − , the guanidinium cation acts as a strong hydrogen‐bonding donor via the guanidine NH 2 and NH groups, with the carboxy groups of the nitrobenzoate group acting as the acceptors. These hydrogen bonds lead to fused R 2 2 (8) and R 6 4 (16) rings, which form corrugated sheets perpendicular to [010].